Suggested Citation: "Front Matter." National Research Council. 2005. Superfund and Mining Megasites: Lessons from the Coeur d'Alene River Basin. Washington, DC: The National Academies Press. doi: 10.17226/11359.

SUPERFUND AND MINING MEGASITES

LESSONS FROM THE COEUR D’ALENE RIVER BASIN

Committee on Superfund Site Assessment and Remediation in the Coeur d’Alene River Basin

Board on Environmental Studies and Toxicology

Division on Earth and Life Studies

NATIONAL RESEARCH COUNCIL OF THE NATIONAL ACADEMIES

THE NATIONAL ACADEMIES PRESS
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Suggested Citation: "Front Matter." National Research Council. 2005. Superfund and Mining Megasites: Lessons from the Coeur d'Alene River Basin. Washington, DC: The National Academies Press. doi: 10.17226/11359.

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Suggested Citation: "Front Matter." National Research Council. 2005. Superfund and Mining Megasites: Lessons from the Coeur d'Alene River Basin. Washington, DC: The National Academies Press. doi: 10.17226/11359.

THE NATIONAL ACADEMIES

Advisers to the Nation on Science, Engineering, and Medicine


The National Academy of Sciences is a private, nonprofit, self-perpetuating society of distinguished scholars engaged in scientific and engineering research, dedicated to the furtherance of science and technology and to their use for the general welfare. Upon the authority of the charter granted to it by the Congress in 1863, the Academy has a mandate that requires it to advise the federal government on scientific and technical matters. Dr. Ralph J. Cicerone is president of the National Academy of Sciences.


The National Academy of Engineering was established in 1964, under the charter of the National Academy of Sciences, as a parallel organization of outstanding engineers. It is autonomous in its administration and in the selection of its members, sharing with the National Academy of Sciences the responsibility for advising the federal government. The National Academy of Engineering also sponsors engineering programs aimed at meeting national needs, encourages education and research, and recognizes the superior achievements of engineers. Dr. Wm. A. Wulf is president of the National Academy of Engineering.


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Suggested Citation: "Front Matter." National Research Council. 2005. Superfund and Mining Megasites: Lessons from the Coeur d'Alene River Basin. Washington, DC: The National Academies Press. doi: 10.17226/11359.

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Suggested Citation: "Front Matter." National Research Council. 2005. Superfund and Mining Megasites: Lessons from the Coeur d'Alene River Basin. Washington, DC: The National Academies Press. doi: 10.17226/11359.

COMMITTEE ON SUPERFUND SITE ASSESSMENT AND REMEDIATION IN THE COEUR D’ALENE RIVER BASIN

Members

DAVID J. TOLLERUD (Chair),

University of Louisville, Louisville, KY

HERBERT L. ALLEN,

University of Delaware, Newark

LAWRENCE W. BARNTHOUSE,

LWB Environmental Services, Oak Ridge, TN

CORALE L. BRIERLEY,

Brierley Consultancy LLC, Highlands Ranch, CO

EDWIN H. CLARK II,

Clean Sites Inc., Washington, DC

THOMAS W. CLARKSON,

University of Rochester, Rochester, NY

EDMUND A.C. CROUCH,

Cambridge Environmental, Inc., Cambridge, MA

ALISON CULLEN,

University of Washington, Seattle

JOSEPH GRAZIANO,

Columbia University, New York, NY

DAVID L. JOHNSON,

State University of New York, Syracuse

RONALD J. KENDALL,

Texas Tech University, Lubbock

JOHN C. KISSEL,

University of Washington, Seattle

THOMAS W. LAPOINT,

University of North Texas, Denton

DAVID W. LAYTON,

University of California, Livermore

C. HERB WARD,

Rice University, Houston, TX

SPENCER WOOD,

Boise State University, Boise, ID

ROBERT WRIGHT,

Children’s Hospital Boston, Boston, MA

Project Staff

KARL E. GUSTAVSON, Study Director

RAYMOND A. WASSEL, Program Director

CAY BUTLER, Editor

MIRSADA KARALIC-LONCAREVIC, Research Associate

OLUKEMI O. YAI, Program Assistant

SAMMY BARDLEY, Librarian

ALEXANDRA STUPPLE, Senior Editorial Assistant

Sponsor

U.S. ENVIRONMENTAL PROTECTION AGENCY

Suggested Citation: "Front Matter." National Research Council. 2005. Superfund and Mining Megasites: Lessons from the Coeur d'Alene River Basin. Washington, DC: The National Academies Press. doi: 10.17226/11359.

BOARD ON ENVIRONMENTAL STUDIES AND TOXICOLOGY1

Members

JONATHAN M. SAMET (Chair),

Johns Hopkins University, Baltimore, MD

RAMÓN ALVAREZ,

Environmental Defense, Austin, TX

THOMAS BURKE,

Johns Hopkins University, Baltimore, MD

JUDITH C. CHOW,

Desert Research Institute, Reno, NV

COSTEL D. DENSON,

University of Delaware, Newark

E. DONALD ELLIOTT,

Willkie Farr & Gallagher LLP, Washington, DC

CHRISTOPHER B. FIELD,

Carnegie Institution of Washington, Stanford, CA

SHERRI W. GOODMAN,

Center for Naval Analyses, Alexandria, VA

JUDITH A. GRAHAM,

American Chemistry Council, Arlington, VA

DANIEL S. GREENBAUM,

Health Effects Institute, Cambridge, MA

ROBERT HUGGETT,

Michigan State University, East Lansing

BARRY L. JOHNSON,

Emory University, Atlanta, GA

JAMES H. JOHNSON,

Howard University, Washington, DC

JUDITH L. MEYER,

University of Georgia, Athens

PATRICK Y. O’BRIEN,

ChevronTexaco Energy Technology Company, Richmond, CA

DOROTHY E. PATTON,

International Life Sciences Institute, Washington, DC

STEWARD T.A. PICKETT,

Institute of Ecosystem Studies, Millbrook, NY

JOSEPH V. RODRICKS,

ENVIRON Corporation, Arlington, VA

ARMISTEAD G. RUSSELL,

Georgia Institute of Technology, Atlanta

MITCHELL J. SMALL,

Carnegie Mellon University, Pittsburgh, PA

LISA SPEER,

Natural Resources Defense Council, New York, NY

KIMBERLY M. THOMPSON,

Harvard School of Public Health, Boston, MA

G. DAVID TILMAN,

University of Minnesota, St. Paul

CHRIS G. WHIPPLE,

ENVIRON Corporation, Emeryville, CA

LAUREN ZEISE,

California Environmental Protection Agency, Oakland

Senior Staff

JAMES J. REISA, Director

DAVID J. POLICANSKY, Scholar

RAYMOND A. WASSEL, Senior Program Officer for Environmental Sciences and Engineering

KULBIR BAKSHI, Senior Program Officer for Toxicology

EILEEN N. ABT, Senior Program Officer for Risk Analysis

K. JOHN HOLMES, Senior Program Officer

SUSAN N.J. MARTEL, Senior Program Officer

SUZANNE VAN DRUNICK, Senior Program Officer

ELLEN K. MANTUS, Senior Program Officer

RUTH E. CROSSGROVE, Senior Editor

1  

This study was planned, overseen, and supported by the Board on Environmental Studies and Toxicology.

Suggested Citation: "Front Matter." National Research Council. 2005. Superfund and Mining Megasites: Lessons from the Coeur d'Alene River Basin. Washington, DC: The National Academies Press. doi: 10.17226/11359.

OTHER REPORTS OF THE BOARD ON ENVIRONMENTAL STUDIES AND TOXICOLOGY

Health Implications of Perchlorate Ingestion (2005)

Air Quality Management in the United States (2004)

Endangered and Threatened Species of the Platte River (2004)

Atlantic Salmon in Maine (2004)

Endangered and Threatened Fishes in the Klamath River Basin (2004)

Cumulative Environmental Effects of Alaska North Slope Oil and Gas Development (2003)

Estimating the Public Health Benefits of Proposed Air Pollution Regulations (2002)

Biosolids Applied to Land: Advancing Standards and Practices (2002)

The Airliner Cabin Environment and Health of Passengers and Crew (2002)

Arsenic in Drinking Water: 2001 Update (2001)

Evaluating Vehicle Emissions Inspection and Maintenance Programs (2001)

Compensating for Wetland Losses Under the Clean Water Act (2001)

A Risk-Management Strategy for PCB-Contaminated Sediments (2001)

Acute Exposure Guideline Levels for Selected Airborne Chemicals (4 volumes, 2000-2004)

Toxicological Effects of Methylmercury (2000)

Strengthening Science at the U.S. Environmental Protection Agency (2000)

Scientific Frontiers in Developmental Toxicology and Risk Assessment (2000)

Ecological Indicators for the Nation (2000)

Waste Incineration and Public Health (1999)

Hormonally Active Agents in the Environment (1999)

Research Priorities for Airborne Particulate Matter (4 volumes, 1998-2004)

The National Research Council’s Committee on Toxicology: The First 50 Years (1997)

Carcinogens and Anticarcinogens in the Human Diet (1996)

Upstream: Salmon and Society in the Pacific Northwest (1996)

Science and the Endangered Species Act (1995)

Wetlands: Characteristics and Boundaries (1995)

Biologic Markers (5 volumes, 1989-1995)

Review of EPA’s Environmental Monitoring and Assessment Program (3 volumes, 1994-1995)

Science and Judgment in Risk Assessment (1994)

Pesticides in the Diets of Infants and Children (1993)

Dolphins and the Tuna Industry (1992)

Suggested Citation: "Front Matter." National Research Council. 2005. Superfund and Mining Megasites: Lessons from the Coeur d'Alene River Basin. Washington, DC: The National Academies Press. doi: 10.17226/11359.

Science and the National Parks (1992)

Human Exposure Assessment for Airborne Pollutants (1991)

Rethinking the Ozone Problem in Urban and Regional Air Pollution (1991)

Decline of the Sea Turtles (1990)


Copies of these reports may be ordered from the National Academies Press
(800) 624-6242 or (202) 334-3313

www.nap.edu

Suggested Citation: "Front Matter." National Research Council. 2005. Superfund and Mining Megasites: Lessons from the Coeur d'Alene River Basin. Washington, DC: The National Academies Press. doi: 10.17226/11359.

Preface

The U.S. Environmental Protection Agency (EPA) was established in 1970 to protect human health and the natural environment. The agency’s mission includes enforcing and implementing environmental laws enacted by Congress, assessing environmental conditions, and solving current and anticipating future environmental issues. To assist EPA in addressing risks associated with chemical emergencies as well as abandoned hazardous waste sites, Congress passed the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) in 1980, better known as the Superfund Act. The Superfund program addresses short- and long-term risks of chemical spills and supports the permanent cleanup and rehabilitation of hazardous waste sites.

In 2002, Congress instructed EPA to ask the National Research Council (NRC) to conduct an independent evaluation of the Coeur d’Alene River basin Superfund site in northern Idaho as a case study to examine EPA’s scientific and technical practices in Superfund megasites, including physical site definition, human and ecologic risk assessment, remedial planning, and decision making. NRC established the Committee on Superfund Site Assessment and Remediation in the Coeur d’Alene River Basin. In this report, the committee analyzes the record of decision and supporting documents from this Superfund site to assess the adequacy and application of EPA’s own Superfund guidance in terms of available scientific and technical knowledge and best practices.

In the course of preparing this report, the committee held five meetings, including public sessions in Washington, DC; Wallace, Idaho; and Spokane, Washington—where local, state, tribal, and federal officials, as well as rep-

Suggested Citation: "Front Matter." National Research Council. 2005. Superfund and Mining Megasites: Lessons from the Coeur d'Alene River Basin. Washington, DC: The National Academies Press. doi: 10.17226/11359.

resentatives from the private sector and nongovernmental organizations, including regulated industries and citizen groups, were invited to meet with the committee and present their views on Superfund activities in the Coeur d’Alene River basin. Interested members of the public were also given an opportunity to speak on these occasions. The following individuals spoke at these meetings: U.S. Senator Larry Craig; U.S. Senator Michael Crapo; U.S. Congressman C. L. “Butch” Otter; Brian Cleary, counsel to Coeur d’Alene tribe; Ernest Stensgar, Chairman of the Coeur d’Alene tribe; Phillip Cernera, Coeur d’Alene tribe; Alfred Nomee, Coeur d’Alene tribe; Ian von Lindern, TerraGraphics Environmental Engineering; John Roland, Washington Department of Ecology; Robert Hanson, Mine Waste program manager; Stephen Allred, director, Idaho Department of Environmental Quality; Ron Roizen, Bill Rust, Frank Frutchey, Lee Haynes, Jack Riggs, Bob Hopper, Fred Brackebusch, Ivan Linscott, Shoshone Natural Resources Coalition Science Committee; Fred Kirschner, Spokane tribe; Rogers Hardy, Citizens Against Rail to Trail/Citizens Advocating Responsible Treatment; Thomas Pedersen, University of Victoria; David Moershel, Spokane physician and president of the Lands Council; Allen Isaacson, professor, Spokane Community College and former U.S. Forest Service supervisory hydrologist for the Idaho Panhandle National Forest; Bruce Lanphear, director, Cincinnati Children’s Environmental Health; Jerry Cobb, Panhandle Health District; Brad Sample, CH2M Hill; David Fortier, environment protection specialist, Bureau of Land Management; Paul Woods, Laura Balistrieri, Stephen Box, Nelson Beyer, U.S. Geological Survey; Daniel Audet, U.S. Fish and Wildlife Service; and Elizabeth Southerland, Michael Gearheard, Sheila Eckman, Anne Dailey, Mary Jane Nearman, Angela Chung, Marc Stifelman, Cami Grandinetti, Bill Adams, EPA.

In addition to the information from those presentations, the committee made use of the peer-reviewed scientific literature; government agency reports; information submitted to the committee by citizens, advocacy groups, and industry; and unpublished database information as well as related statistics and data directly obtained from EPA and the states of Idaho and Washington.

This report consists of nine chapters. The first chapter provides an overview of the committee’s charge, the issues related to this charge, and the approach the committee took in completing its task. Chapters 2 and 3 review the history of the Coeur d’Alene mining district and the relationship between the biologic, human, and physical environments in the river basin. Chapters 4-8 review scientific and technical questions relating to the remedial investigation, human and ecologic risk assessments, and remedial decisions set forth in EPA’s record of decision for the site and the supporting documents. Finally, Chapter 9 discusses lessons learned from the Coeur

Suggested Citation: "Front Matter." National Research Council. 2005. Superfund and Mining Megasites: Lessons from the Coeur d'Alene River Basin. Washington, DC: The National Academies Press. doi: 10.17226/11359.

d’Alene experience and suggests a new paradigm for addressing environmental and health concerns at large complex mining sites.

We wish to thank Earl Bennett, University of Idaho, and Teresa Bowers, Gradient Corporation, for their valuable service while they served on the committee. The committee is also grateful for the assistance of NRC staff in preparing this report: Karl Gustavson, study director; James Reisa, director of the Board on Environmental Studies and Toxicology; Ray Wassel, program director; Ruth E. Crossgrove, senior editor; Cay Butler, editor; Mirsada Karalic-Loncarevic and Bryan Shipley, research associates; and Olukemi Yai, program assistant; as well as John Brown, Emily Brady, Dominic Brose, Alexandra Stupple, and others who supported the project as part of the Board’s staff.

Finally, I thank the members of the committee for their dedicated efforts throughout the development of this report.


David J. Tollerud, MD, MPH

Chair, Committee on Superfund Site Assessment and
Remediation in the Coeur d’Alene River Basin

Suggested Citation: "Front Matter." National Research Council. 2005. Superfund and Mining Megasites: Lessons from the Coeur d'Alene River Basin. Washington, DC: The National Academies Press. doi: 10.17226/11359.

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Suggested Citation: "Front Matter." National Research Council. 2005. Superfund and Mining Megasites: Lessons from the Coeur d'Alene River Basin. Washington, DC: The National Academies Press. doi: 10.17226/11359.

Acknowledgment of Review Participants

This report has been reviewed in draft form by individuals chosen for their diverse perspectives and technical expertise, in accordance with procedures approved by NRC’s Report Review Committee. The purpose of this independent review is to provide candid and critical comments that will assist the institution in making its published report as sound as possible and to ensure that the report meets institutional standards for objectivity, evidence, and responsiveness to the study charge. The review comments and draft manuscript remain confidential to protect the integrity of the deliberative process. We wish to thank the following individuals for their review of this report: Craig Boreiko, International Lead Zinc Research Organization; Stephen E. Box, U.S. Geological Survey; Gary Diamond, Syracuse Research Corporation; Lorne G. Everett, Lakehead University and Shaw Environmental & Infrastructure, Inc.; Michael C. Kavanaugh, Malcolm Pirnie, Inc.; Phillip E. LaMoreaux, P.E. LaMoreaux & Associates; Bruce P. Lanphear, Cincinnati Children’s Hospital Medical Center; Dwayne Moore, Cantox Environmental, Inc.; Darrell K. Nordstrom, U.S. Geological Survey; Dianne Nielson, Utah Department of Environmental Quality; Benjamin Parkhurst, HAF Inc.; Katherine N. Probst, Resources for the Future; Joyce S. Tsuji, Exponent, Inc.; and Stephen Washburn, ENVIRON.

Although the reviewers listed above have provided many constructive comments and suggestions, they were not asked to endorse the conclusions or recommendations, nor did they see the final draft of the report before its release. The review of this report was overseen by Dr. David G. Hoel, Medical University of South Carolina, and Dr. Perry L. McCarty, Stanford University. Appointed by the NRC, they were responsible for making certain

Suggested Citation: "Front Matter." National Research Council. 2005. Superfund and Mining Megasites: Lessons from the Coeur d'Alene River Basin. Washington, DC: The National Academies Press. doi: 10.17226/11359.

that an independent examination of this report was carried out in accordance with institutional procedures and that all review comments were carefully considered. Responsibility for the final content of this report rests entirely with the authoring committee and the institution.

Suggested Citation: "Front Matter." National Research Council. 2005. Superfund and Mining Megasites: Lessons from the Coeur d'Alene River Basin. Washington, DC: The National Academies Press. doi: 10.17226/11359.
Suggested Citation: "Front Matter." National Research Council. 2005. Superfund and Mining Megasites: Lessons from the Coeur d'Alene River Basin. Washington, DC: The National Academies Press. doi: 10.17226/11359.
   

 Determining Background Concentrations,

 

122

   

 Chemical Speciation and Transport of Metals,

 

128

   

 Conclusions and Recommendations,

 

149

   

 References,

 

153

5

 

HUMAN HEALTH RISK ASSESSMENT IN THE COEUR D’ALENE RIVER BASIN

 

161

   

 Introduction,

 

161

   

 Chemicals of Concern in the Coeur d’Alene River Basin: Hazard Identification,

 

165

   

 Approach Used to Assess Human Hazards: Exposure Assessment,

 

167

   

 Human Health: Toxicity Assessment,

 

170

   

 Risk Characterization,

 

172

   

 Plausible Health Risks from Living in the Coeur d’Alene River Basin,

 

175

   

 Blood Lead Studies in the Coeur d’Alene River Basin,

 

180

   

 Strategies to Manage the Risks to Human Health,

 

191

   

 Adherence of the Proposed Actions to Superfund Guidance,

 

209

   

 Conclusions and Recommendations,

 

210

   

 References,

 

214

6

 

HUMAN HEALTH RISK ASSESSMENT: LEAD EXPOSURE AND UPTAKE—USE OF THE IEUBK MODEL

 

223

   

 Model Development Background,

 

223

   

 Description of the IEUBK Model,

 

229

   

 Application of IEUBK to OU-3 (Coeur d’Alene River Basin),

 

241

   

 Conclusions and Recommendations,

 

269

   

 References,

 

275

7

 

ECOLOGICAL RISK ASSESSMENT

 

284

   

 Introduction,

 

284

   

 Consistency of the ERA with EPA Guidance Concerning the ERA Process,

 

286

   

 Consistency of the ERA with Best Scientific Practice,

 

293

   

 Validity of Conclusions,

 

313

   

 Use of the ERA in Risk Management,

 

314

   

 Conclusions and Recommendations,

 

319

   

 References,

 

322

8

 

REMEDIATION OBJECTIVES AND APPROACHES

 

327

   

 Introduction,

 

327

   

 Remediation Objectives and Incorporation of Cleanup Goals,

 

328

   

 Description and Comparison of Remedial Alternatives,

 

329

   

 Selected Remedy: Geographic Areas, Levels of Remediation, and Remediation Plans,

 

341

Suggested Citation: "Front Matter." National Research Council. 2005. Superfund and Mining Megasites: Lessons from the Coeur d'Alene River Basin. Washington, DC: The National Academies Press. doi: 10.17226/11359.

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Suggested Citation: "Front Matter." National Research Council. 2005. Superfund and Mining Megasites: Lessons from the Coeur d'Alene River Basin. Washington, DC: The National Academies Press. doi: 10.17226/11359.



SUPERFUND
AND MINING MEGASITES

LESSONS FROM THE COEUR D’ALENE RIVER BASIN

Suggested Citation: "Front Matter." National Research Council. 2005. Superfund and Mining Megasites: Lessons from the Coeur d'Alene River Basin. Washington, DC: The National Academies Press. doi: 10.17226/11359.

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